Chemical Engineering June 2016 - 49

SiLT denSiTy index
Silt density index (SdI) is a sensitive method for determining the ability of a filter to remove
colloidal particles. SdI is used extensively as a criterion in minimizing fouling of reverse
osmosis membranes. The lower the SdI value, the cleaner the stream. EPFs can be used
to pretreat water before it enters Ro membranes. Pretreatment with EPF reduced nanoparticle
fouling of microfiltration (MF) membrane by about 2% (with pretreatment), as compared
to 80% (with no pretreatment) [6].
Manufacturers of Ro membranes recommend that the stream be prefiltered so that it has
an SdI factor less than 3.0. Typically " 1-μm absolute " [14] filters have an SdI of about 4 to 5.
Manufacturers of hollow fiber membrane filters claim SdIs in the range of 1.75 to 2.25. SdI
measurements of effluents from the media with nanoscale alumina features media range
from 0.5 to 1.0. Turbidity as well as SdI tests have confirmed that the extent of shedding of
nanoscale particles from the nano-alumina-type filters into effluent streams is minimal.
the media thickness is 0.8 mm.
The high surface area of the nanoscale
alumina fibers, plus their high
zeta potential, produce strong electrostatic
and electrokinetic fields
that influence the flow of particles
as far as 1 µm away from the surface
of the media. zeta potential is
a measure of the magnitude of the
electrostatic attraction or repulsion
between particles. The field therefore
overlaps the flow channels of
the 2-µm-pore-size media. Since
the particle flows through a tortuous
path of approximately 400 pores
across the media, there is a high
probability of particle capture.
Since the electropositive nanoAl
fibers are dispersed and fixed in
place via electroadhesive forces,
particles have easy access to the
charged surface. Powdered activated
carbon (Figure 1, center) or
nanoparticles such as nano-silica
can be retained in the nanoAl structure.
The pore size of the non-woven
media is 2 μm, yet the filter can remove
suspended solids as small as
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viruses (typically 20-30 nm in diameter)
and does so at high flowrates
and at salinity values up to 3.4 M
of naCl (near saturation at 300,000
ppm) and at pH values in the range
from 4 to 10.
Filtering bacteria and viruses
The removal of bacteria and viruses
from water in CPI applications is important
for several reasons. Aside
from being potentially pathogenic
contaminants, microbes are also
foulants in HvAC (heating, ventilation
and air conditioning) and other systems.
Bacteria can also play a role in
corrosion (Thiobacillus ferrooxidans
is known to feed on iron and cause
corrosion, for example). Microbes
also have a tendency to attach to
surfaces and form biofilms, which
may not be affected by disinfecting
efforts, such as the use of free chlorine,
even at concentrations of several
ppm [13].
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Chemical Engineering June 2016

Table of Contents for the Digital Edition of Chemical Engineering June 2016

Contents
Chemical Engineering June 2016 - Cover1
Chemical Engineering June 2016 - Cover2
Chemical Engineering June 2016 - Contents
Chemical Engineering June 2016 - 2
Chemical Engineering June 2016 - 3
Chemical Engineering June 2016 - 4
Chemical Engineering June 2016 - 5
Chemical Engineering June 2016 - 6
Chemical Engineering June 2016 - 7
Chemical Engineering June 2016 - 8
Chemical Engineering June 2016 - 9
Chemical Engineering June 2016 - 10
Chemical Engineering June 2016 - 11
Chemical Engineering June 2016 - 12
Chemical Engineering June 2016 - 13
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Chemical Engineering June 2016 - 15
Chemical Engineering June 2016 - 16
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Chemical Engineering June 2016 - 19
Chemical Engineering June 2016 - 20
Chemical Engineering June 2016 - 21
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Chemical Engineering June 2016 - 24
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Chemical Engineering June 2016 - 26
Chemical Engineering June 2016 - 27
Chemical Engineering June 2016 - 28
Chemical Engineering June 2016 - 29
Chemical Engineering June 2016 - 30
Chemical Engineering June 2016 - 31
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Chemical Engineering June 2016 - 33
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Chemical Engineering June 2016 - 35
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Chemical Engineering June 2016 - 76
Chemical Engineering June 2016 - Cover3
Chemical Engineering June 2016 - Cover4
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