Chemical Engineering June 2020 - 47

dian starting hcl concentration for
the bath is 15%, the median concentration
of spent acid would average
7%. the fe concentration in
the spent acid varies based on the
type of rust dissolved. the reactions
below depict oxidized rust (orange)
and an feo (green) surface rust in
steel processing.
6hcl (aq) + fe2o3 (s) →
2fecl3 (aq) + 3h2o (l)
2hcl (aq) + feo(s) →
fecl2 (aq) + h2o (g)
(4)
(5)
Spent acid
Since most of the iron in spent acid
solutions tests as fe (ii), the second
equation predominates.
Some production plants are designed
with several large pickling
tanks to allow extended pickling
time. the primary purpose of this is
to consume as much hcl as possible
before disposal or treatment.
another method to maximize acid
Total
HCI
FeCl2
H20
208.00 kg/h
12.50
31.25
164.25
Figure 4. This pyrohydrolysis process
handles 5 metric tons per day (m.t./d) of
spent hydrochloric acid
usage is employed by many push/
pull sheet and coil pickling operations.
the continuous strip steel
travels countercurrent to the flow
of hydrochloric acid, cleaning the
the
Total
HCI
FeO
H20
Scrubber
Rinse
water
Total
HCI
FeCl2
H20
272.00 kg/h
0.00
6.00
256.00
Conc.
refeed
Total
HCI
FeCl2
H20
169.00 kg/h
4.00
37.00
128.00
Venturi
Fuel & air
Surge
Total
HCI
FeCl2
H20
169.25 kg/h
30.25
00.00
139.00
Iron Oxide
conc.
23.70 kg/h
0.00
23.70
0.00
surface of the steel. the final countercurrent
pickle tank is heated to
increase
reactivity and consumption
of the acid. in contrast,
most wire, tube and metal finishing
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ChemiCal engineering www.Chemengonline.Com June 2020
47
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Chemical Engineering June 2020

Table of Contents for the Digital Edition of Chemical Engineering June 2020

Contents
Chemical Engineering June 2020 - Cover1
Chemical Engineering June 2020 - Cover2
Chemical Engineering June 2020 - Contents
Chemical Engineering June 2020 - 2
Chemical Engineering June 2020 - 3
Chemical Engineering June 2020 - 4
Chemical Engineering June 2020 - 5
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Chemical Engineering June 2020 - 7
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Chemical Engineering June 2020 - Cover3
Chemical Engineering June 2020 - Cover4
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