Gas Processes Handbook - 70
2019 GAS PROCESSES HANDBOOK
PROCESS CATEGORIES
COMPANY INDEX
HYDROGEN
Application: Production of H2 from hydrocarbon (HC) feedstocks, by steam reforming.
Feedstocks: Ranging from natural gas to heavy naphtha, as well as potential refinery
offgases. Many recent refinery hydrogen (H2 ) plants have multiple-feedstock flexibility,
either in terms of backup, or alternative or mixed feed. Automatic feedstock changeover has also successfully been applied by TechnipFMC in several modern plants with
multiple-feedstock flexibility.
Description: The generic flowsheet consists of feed pretreatment, pre-reforming
(optional), steam-HC reforming, shift conversion and H2 purification by pressure swing
adsorption (PSA). However, it is often tailored to satisfy specific requirements.
Feed pretreatment normally involves removal of sulfur, chlorine and other
catalyst poisons after preheating to an appropriate level.
The treated feed gas mixed with process steam is reformed in a fired reformer
(with adiabatic pre-reformer upstream, if used) after necessary superheating. The net
reforming reactions are strongly endothermic. Heat is supplied by combusting PSA
purge gas, supplemented by makeup fuel in multiple burners in a top-fired furnace.
Reforming severity is optimized for each specific case. Waste heat from reformed
gas is recovered through steam generation before the water-gas shift conversion.
Most of the CO is further converted to H2 in the shift reactor. Process condensate
resulting from heat recovery and cooling is separated and generally reused in the
steam system after necessary treatment. The entire steam generation is usually on
natural circulation, which adds to higher reliability. The gas flows to the PSA unit,
which provides high-purity H2 product (up to < 1 ppm CO) at near-inlet pressures.
Typical specific energy consumption based on feed + fuel - export steam ranges
between 3 Gcal/KNm3 and 3.5 Gcal/KNm3 of H2 (330 Btu/sft3-370 Btu/sft3) on a lower
heating valve basis, depending upon feedstock, plant capacity, optimization criteria
and steam export requirements.
Recent advances include integration of H2 recovery and generation, and
recuperative reforming in a Technip Parallel Reformer (TPR®), which is especially
suitable for capacity retrofits.
Process steam
Feedstock
Feed
pretreatment
Steam
system
Prereformer
(optional)
PSA purge gas and makeup fuel
Export steam
Vent steam
Reformer
Air
preheater
Hydrogen
Recycle H2
Steam
sys.
Steam
system
Process
coils
BFW preparation
Shift
conv.
Process
condensate
Cooling
train
Feed or
steam
Air
Demineralized
water
Dosing
Purge gas
fuel to
reformer
PSA
unit
H2 prod.
Recycle H2
Installations: TechnipFMC's H2 plant technology has been applied in more than
270 plants worldwide. Most installations are for refinery application with basic
features for high reliability and optimized cost.
Website: www.technipfmc.com
Licensor: TechnipFMC
Contact: ProcessTechnology@TechnipFMC.com
Copyright © 2019 Gulf Energy Information. All rights reserved.
https://www.hydrocarbonprocessing.com/
http://www.technipfmc.com
Gas Processes Handbook
Table of Contents for the Digital Edition of Gas Processes Handbook
Contents
Gas Processes Handbook - 1
Gas Processes Handbook - 2
Gas Processes Handbook - 3
Gas Processes Handbook - Contents
Gas Processes Handbook - 5
Gas Processes Handbook - 6
Gas Processes Handbook - 7
Gas Processes Handbook - 8
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