NFPA Journal - May/June 2013 - (Page 72)
— . CODES IN REVIEW . —
NFPA 704
3
4
TWO APPROACHES, ONE HAZARD
2
EPICHLOROHYDRIN 1
UN No. 2023
3
2
DANGER
4 Flammable liquid and vapor. Toxic if swallowed.
Toxic in contact with skin. Causes severe skin burns
and eye damage. May cause an allergic skin reaction.
May cause cancer.
5 Do not breathe dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection
Fill Weight: 18.52 lbs.
Gross Weight: 20 lbs.
Expiration Date: 1/13/2018
6
Lot Number: A0323111323
Fill Date: 1/15/2012
HYPOTHETICAL CHEMICAL CORP. • Quincy, Massachusetts, USA
related hazards addressed by NFPA 704.
The NFPA system enjoys a much broader application as a hazardous chemical
information resource than originally
envisioned. Much of that increased use
occurred during the 30 years following the issuance of the original HCS
standard by OSHA in 1983. Since then,
employers have utilized the NFPA 704
system widely in their efforts to comply
with the HCS requirement for educating employees. Because the NFPA 704
72
NFPA JOURNAL MAY/JUNE 2013
201
system limits its application to acute
hazards, it would not be sufficient to
comply with the HCS requirements
without some augmentation. OSHA
acknowledged that employers could
use the NFPA 704 system as a HazCom
compliance resource, provided their
program addressed the differences
between the systems and employees
received training on those differences.
In the 1980s, the United Nations
began holding discussions on the cre-
The compound epichlorohydrin is
used in a variety of industries for the
production of glycerol, plastics, epoxy
glues and resins, and elastomers. It
is highly reactive and is a significant
health hazard.
The NFPA 704 hazard rating label for
epichlorohydrin, at left, includes a “4”
for the blue health hazard, the highest
rating, meaning the hazard can be
lethal. The red flammability hazard is
a “3,” meaning it can be ignited under
almost all ambient temperatures. The
yellow instability hazard is rated as a
“2,” meaning violent chemical change
is possible at high temperatures or
pressures. The white special hazard
space is empty because the compound poses no special hazard.
The U.N.-GHS hazard labeling standard adopted by OHSA takes a different approach. Each label requires,
1) a product identifier and identification number, in this case the name of
the compound and its U.N. identification number; 2) a signal word, either
danger or warning; 3) pictograms
depicting associated hazards, in this
case, clockwise from top, flammable,
toxic if swallowed, skin burns and
eye damage, may cause cancer;
4) a written list of associated hazards; 5) precautionary statements
related to the hazard; and 6) supplier
information. The pictograms do not
include numbered hazard ratings, but
supporting information in the safety
data sheets does include numerical
ratings, which are organized with “1”
being the most serious level of hazard—the opposite of the hazard rating
scale used in NFPA 704 and a source
of potential confusion for users.
ation of a new “globally harmonized
system,” a single system for evaluating
and identifying chemical hazards that
would be adopted and used to protect
workers and the environment worldwide. OSHA represented the United
States during these negotiations.
The result was the set of guidelines
described in the U.N. document “Globally Harmonized System of Classification and Labeling of Chemicals,” commonly referred to as The Purple Book,
Table of Contents for the Digital Edition of NFPA Journal - May/June 2013
NFPA Journal - May/June 2013
Contents
First Word
In a Flash
Perspectives
Firewatch
Research
Heads Up
Structural Ops
In Compliance
Buzzwords
Outreach
Electrical Safety
Wildfire Watch
Treasurer's Report
Work in Progress
Amping It Up
Drill Team
Working Together
Code Process 2.0
Routine Maintenance
Here, There, Everywhere
Section Spotlight
Expo Preview: Exhibitors' Showcase
Looking Back
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