Magnetics Business & Technology - Spring 2013 - (Page 4)
EDITOR’S CHOICE
Iron-Based Superconductors Set New Performance Records
The road to a sustainably powered future may be paved with superconductors. When
chilled to frigid temperatures hundreds of degrees Celsius below zero, these remarkable
materials are singularly capable of perfectly conducting electric current. To meet growing
global energy demands, the entire energy infrastructure would benefit tremendously from
incorporating new electricity generation, storage and delivery technologies that use superconducting wires. But strict limits on temperature, high manufacturing costs and the dampening
effects of high-magnetic fields currently impede
widespread adoption.
Now, a collaboration led by scientists at the US
DOE’s Brookhaven National Laboratory have
created a high performance iron-based superconducting wire that opens new pathways for some of
the most essential and energy-intensive technologies in the world. These custom-grown materials
carry tremendous current under exceptionally high
magnetic fields, an order of magnitude higher than
those found in wind turbines, magnetic resonance
imaging (MRI) machines and even particle accelerators. The results demonstrate a unique layered
structure that outperforms competing low-temperature superconducting wires, while avoiding the
manufacturing costs associated with high-temper- Brookhaven physicists Weidong Si (left)
and Qiang Li look into the vacuum chamature superconductor (HTS) alternatives.
ber where the new high-field iron-based
“With the focused effort of this collaboration, superconductors are made through a prowe made a major breakthrough in iron chalcogen- cess called pulsed-laser deposition.
ide-based superconducting films that not only sets
the record for maximum critical current under high magnetic fields, but also raises the
operating temperature for the material,” said Brookhaven Lab physicist Weidong Si. “That
could mean conducting more electricity in a wide range of technologies while potentially
using less energy to cool down the superconducting wire.”
Copper-oxide (cuprate) high-temperature superconductors are a leading candidate for
advanced energy applications, but these ceramic-based materials are very brittle and require a complicated and expensive multilayer synthesis process. Beyond that, anisotropies,
structural asymmetries that prevent current from flowing evenly in different directions
across a material, limit overall efficiency in these compounds.
Iron-based superconductors, however, are mechanically semi-metallic and therefore
considerably less fragile. They can also be more easily shaped into the kinds of long wires
needed in devices like massive offshore wind turbines, and they exhibit nearly isotropic
behavior in magnetic fields, which allows for easier technology integration.
The scientists synthesized this novel film of iron, selenium and tellurium to push existing
performance parameters. In addition to the raw materials being relatively inexpensive, the
synthesis process itself can be performed at just half the temperature of cuprate-based HTS
alternatives, or approximately 400°C.
The team used a thin film fabrication technique called pulsed-laser deposition, which
uses a high-power laser to vaporize materials that are then collected in layers on a substrate. This complex technique is a bit like carefully collecting the gas as it rises above a
boiling pot, only with nearly atomic-level precision.
“A key breakthrough here is the discovery that adding layers of cerium-oxide in between
the films and substrates dramatically increased the superconductor’s critical current density, or maximum electricity load, as well as the critical temperature at which the material becomes superconducting,” said Brookhaven Lab physicist Qiang Li, head of the Advanced
Energy Materials Group and leader of this study. “That critical temperature threshold rose
30 percent over the same compound made without this layering process, still a very cold
4
Magnetics Business & Technology • Spring 2013
Volume 12, Issue 1
Editor & Publisher
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Table of Contents for the Digital Edition of Magnetics Business & Technology - Spring 2013
Magnetics Business & Technology - Spring 2013
Editor's Choice
Dysprosium-Free Rare Earth Magnets for High Temperature Applications
Research & Development
Simulating the Toyota Prius Electric Motor
Magnets • Materials • Measurement
Application • Component Developments
Industry News
Marketplace/Advertising Index
Spontaneous Thoughts: Dysprosium 2.0
Magnetics Business & Technology - Spring 2013
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